A solution containing Mn²+, Fe²+, Zn²+ and Hg²+ with a molar concentration of 10-³ M each is treated with 10-¹⁶M sulphide ion solution. Which ions will precipitate first if Ksp of MnS, FeS, ZnS and HgS are 10-¹⁵, 10-²³ 10-²⁰ and 10-⁵⁴ respectively?
(1)FeS 
(2)MnS
(3)HgS
(4)ZnS

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